Radon in water mystery		This is 30 year old data is from 10 wells in Maine measured over 3 weeks showing a variability of about 1/2 to double over 3 weeks.  Of course this is Maine.
Your results are a lot greater.   Getting a precise water sample takes a precise method for sure.  In my last research I used a hose connection at the indoor well tank faucet routed into a 5 gallon bucket.  I set volume low on the hose and when the there was enough water in the bottom of the bucket I placed hose into the sample vial under water and then capped it under water.  Then repeated with a second vial.  I got good precision between the two samples.  But you said you also had good duplicate precision so that would indicate your method is good.
1		         3,090	         1,420	          117%
2	   	       21,200	       12,400	            71%
3	     	       43,600	       24,900	            75%
4	    	       66,400	       18,900	          251%
5	     	       85,000	       69,238	            23%
6	               99,200	       40,781	           143%
7	               125,000	       95,549	             31%
8	    	     128,000    	     107,196	             19%
9	    	     164,000	     125,603	             31%
10		  1,080,000	     758,760	             42%